The Utilization of Triacontyl-Bonded Silica Coated with Imidazolium Ions for Capillary Ion Chromatographic Determination of Inorganic Anions
نویسندگان
چکیده
This paper describes the separation and detection of five inorganic anions (I - , BrO3 NO2 Br NO3 -) by capillary ion chromatography using 1-alkyl-3-methylimidazolium-coated columns UV at 210 nm. The salts imidazolium (IM) ions (C2-, C4-, C6-, C8-, C10-, C18-IMs) are a family ionic liquids were newly examined as permanent coating reagents on triacontyl (C30) -bonded silica reversed phase column. When 40 mM NaCl aqueous solution was used an eluent, elution time these increased with length alkyl chain between C2- C10-IMs, but turned to decrease C18-IM. Good faster separations attained C18-IM-coated column 150 in 25%(v/v) acetonitrile-75%(v/v) water. method successfully applied determination nitrite, bromide, nitrate seawater river
منابع مشابه
Determination of inorganic anions by capillary ion-exchange chromatography using polyethylenimine-coated octadecyl-bonded phases.
The utility of a cationic polymer polyethylenimines (PEI) for coating some commercially available silica-based stationary phases packed in capillaries of 0.32 mm i.d. and 10 cm long was studied for the separation and direct UV detection of inorganic anions (iodate, bromate, nitrite, bromide, and nitrate ions). With a super-endcapped octadecylated silica stationary phase, which yielded the best...
متن کامل[The simultaneous determination of inorganic anions using an ion chromatographic method: comparisons with colorimetric assays].
متن کامل
Fast ion chromatography of inorganic anions and cations on a lysine bonded porous silica monolith.
A 0.46 cm x 10.0 cm silica monolith column was modified through the in situ covalent attachment of lysine (2,6-diaminohexanoic acid) groups. Due to the zwitterionic nature of the resultant stationary phase, the modified monolithic column contained both cation and anion exchange capacity. In the case of cation exchange, the capacity was found to be relatively low at between 5 and 6.5 micromoles ...
متن کاملRapid separation of inorganic anions by capillary ion chromatography using monolithic silica columns modified with dilauryldimethylammonium ion.
The rapid separation of inorganic anions was determined by capillary ion chromatography using monolithic silica capillary columns modified with dilauryldimethylammonium bromide. The stability of the modified stationary phase was satisfactory owing to a strong hydrophobic interaction between the lauryl groups of the reagent, even if the eluent did not contain dilauryldimethylammonium ion. Bromid...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chromatography
سال: 2021
ISSN: ['1342-8284', '1348-3315']
DOI: https://doi.org/10.15583/jpchrom.2021.009