The Utilization of Triacontyl-Bonded Silica Coated with Imidazolium Ions for Capillary Ion Chromatographic Determination of Inorganic Anions

نویسندگان

چکیده

This paper describes the separation and detection of five inorganic anions (I - , BrO3 NO2 Br NO3 -) by capillary ion chromatography using 1-alkyl-3-methylimidazolium-coated columns UV at 210 nm. The salts imidazolium (IM) ions (C2-, C4-, C6-, C8-, C10-, C18-IMs) are a family ionic liquids were newly examined as permanent coating reagents on triacontyl (C30) -bonded silica reversed phase column. When 40 mM NaCl aqueous solution was used an eluent, elution time these increased with length alkyl chain between C2- C10-IMs, but turned to decrease C18-IM. Good faster separations attained C18-IM-coated column 150 in 25%(v/v) acetonitrile-75%(v/v) water. method successfully applied determination nitrite, bromide, nitrate seawater river

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ژورنال

عنوان ژورنال: Chromatography

سال: 2021

ISSN: ['1342-8284', '1348-3315']

DOI: https://doi.org/10.15583/jpchrom.2021.009